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The main difference between a food chain and a food web is simplicity and connections. Learn here food chain vs food web with examples. Learn the difference between food chain and food web, two ways of representing the energy flow in ecosystems. Compare the number of trophic levels, links, and organisms in each, and how they affect adaptability and competitiveness. The main difference between food chain and food web is that the food chain is a linear sequence of organisms through which the energy and nutrients pass whereas the food web is a complex of interconnected food chains of a particular ecosystem. While food chains and food webs both elucidate trophic relationships within ecosystems, they differ significantly in scope, structure, and complexity.