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This is the geometric isomer definition, with an explanation of the term and several examples of geometric isomerism. Learn what geometric isomerism is and how to recognize it in molecules with carbon-carbon double bonds. See examples of cis and trans isomers and how to draw them correctly. Geometrical Isomerism in Square Planar Complexes Trans-isomer is a square planar complex with two similar ligands at opposite locations (180 o apart), whereas cis-isomer is a square planar complex with similar ligands at adjacent positions (90 o apart). Geometrical Isomerism (in complex with 6-Coordinate Bond) or Octahedral Complexes We know that the shape of a complex compound with a core atom and a coordination number of 6 is octahedral. Complexes of type [MA4B2], where A and B are ... Cis–trans isomerism, also known as geometric isomerism, describes certain arrangements of atoms within molecules. The prefixes " cis " and " trans " are from Latin: "this side of" and "the other side of", respectively. [1]